Search results for "thermal [correlation function]"
showing 10 items of 1923 documents
Microcanonical Determination of the Interface Tension of Flat and Curved Interfaces from Monte Carlo Simulations
2012
The investigation of phase coexistence in systems with multi-component order parameters in finite systems is discussed, and as a generic example, Monte Carlo simulations of the two-dimensional q-state Potts model (q=30) on LxL square lattices (40<=L<=100) are presented. It is shown that the microcanonical ensemble is well-suited both to find the precise location of the first order phase transition and to obtain an accurate estimate for the interfacial free energy between coexisting ordered and disordered phases. For this purpose, a microcanonical version of the heatbath algorithm is implemented. The finite size behaviour of the loop in the curve describing the inverse temperature vers…
Relativistic kinematic approach to the classical ideal gas
2019
he necessary and sufficient conditions for a unit time-like vector field to be the unit velocity of a classical ideal gas are obtained. In a recent paper [Coll, Ferrando and S\'aez, Phys. Rev D {\bf 99} (2019)] we have offered a purely hydrodynamic description of a classical ideal gas. Here we take one more step in reducing the number of variables necessary to characterize these media by showing that a plainly kinematic description can be obtained. We apply the results to obtain test solutions to the hydrodynamic equation that model the evolution in local thermal equilibrium of a classical ideal gas. \end{abstract}
Thermodynamic class II Szekeres-Szafron solutions. Singular models
2019
A family of parabolic Szekeres-Szafron class II solutions in local thermal equilibrium is studied and their associated thermodynamics are obtained. The subfamily with the hydrodynamic behavior of a generic ideal gas (defined by the equation of state $p = k n \Theta$) results to be an inhomogeneous generalization of flat FLRW $\gamma$-law models. Three significative interpretations that follow on from the choice of three specific thermodynamic schemes are analyzed in depth. First, the generic ideal gas in local thermal equilibrium; this interpretation leads to an inhomogeneous temperature $\Theta$. Second, the thermodynamics with homogeneous temperature considered by Lima and Tiomno (CQG 6 1…
Local thermal equilibrium and ideal gas Stephani universes
2005
The Stephani universes that can be interpreted as an ideal gas evolving in local thermal equilibrium are determined. Five classes of thermodynamic schemes are admissible, which give rise to five classes of regular models and three classes of singular models. No Stephani universes exist representing an exact solution to a classical ideal gas (one for which the internal energy is proportional to the temperature). But some Stephani universes may approximate a classical ideal gas at first order in the temperature: all of them are obtained. Finally, some features about the physical behavior of the models are pointed out.
Computer Simulation Studies of Chain Dynamics in Polymer Brushes
2012
Center-of-mass and single monomer motion in grafted chains comprising a strongly stretched polymer brush in thermal equilibrium are studied by large scale molecular dynamics and Monte Carlo simulations of a coarse-grained model. Good solvent conditions are assumed. Our findings seriously question earlier theoretical predictions about the relaxation described by Rouse dynamics of brush coatings. Thus, the correlation functions of parallel and perpendicular components of the mean distance of the center-of-mass from the grafting site, the squared gyration radius and end-to-end distance, are found to deviate strongly from a simple exponential decay. While the relaxation times extracted from the…
Transition probabilities for some infrared O I spectral lines—Application for determining excitation temperatures in low temperature plasmas
2008
Intensities of selected spectral transitions of neutral oxygen emitted from a wall-stabilized arc have been measured. Applying reliable transition probability data taken from literature, Boltzmann plots have been constructed and the temperatures of the plasma have been obtained. At arc plasma conditions ensuring partial local thermal equilibrium, transition probabilities for 4 O I spectral lines from the near infrared spectral range have been obtained. These new results, together with data for two other studied O I spectral lines taken from the National Institute of Standards and Technology data base, are proposed as a suitable set of transition probabilities applicable for diagnostics of l…
Quantitative interpretation of the red edge excitation (REE) effect of 9,9′-bianthryl in polyisobutene by band shape analysis of the temperature-depe…
1994
Optical fluorescence spectra of 9,9′-bianthryl (BA) in polyisobutene (PIB) were measured as a function of the excitation wavelength at various temperatures between 210 and 293 K. Irradiation at the red edge of the absorption spectra selectively excites distinct conformers with respect to the torsional angle. This leads to a strong dependence of the vibronic band shape of the fluorescence spectra on the excitation wavelength. The marked temperature dependence of the band shape may be attributed to the viscosity-dependent deceleration of the torsional relaxation of BA in the highly viscous polymer which prevents the excited state ensemble from reaching thermal equilibrium. The predominant bro…
Atomistic Simulation of Transport Phenomena in Simple and Complex Fluids and Fluid Mixtures
2003
Computer simulations of fluids in thermal equilibrium can yield information on transport coefficients such as self—diffusion and interdiffusion coefficients, viscosity, and thermal conductivity. While the estimation of self—diffusion coefficients from the mean square displacements of the respective particles is rather straightforward, the estimation of other transport coefficients is less straightforward, and can be based on either an analysis of time correlation functions of the appropriate collective variables, or on nonequilibrium techniques where the linear response to appropriate perturbations is measured.
THERMOGRAPHIC CHARACTERIZATION OF A LANDFILL TROUGH AN UNMANNED AERIAL VEHICLE
2019
The use of the thermal imaging camera for Unmanned Aerial Vehicle (UAV) survey is to date very common for environmental analysis, especially if high spatial resolution images are required. Some analyses require images to be acquired close to sunrise, to avoid the influence of the incident solar radiation on the surface temperature, as in the case of a landfill survey. Indeed, thermal anomalies due to generated landfill biogas can be characterized once other heat sources are excluded. In this framework, thermal images need to be processed similarly to optical images by typical photogrammetric workflows producing both a Digital Surface Model (DSM) and an ortho-image. The low spatial resolutio…
Effect of perspiration on skin temperature measurements by infrared thermography and contact thermometry during aerobic cycling
2015
[EN] The aim of the present study was to compare infrared thermography and thermal contact sensors for measuring skin temperature during cycling in a moderate environment. Fourteen cyclists performed a 45-mM cycling test at 50% of peak power output. Skin temperatures were simultaneously recorded by infrared thermography and thermal contact sensors before and immediately after cycling activity as well as after 10 min cooling-down, representing different skin wetness and blood perfusion states. Additionally, surface temperature during well controlled dry and wet heat exchange (avoiding thermoregulatory responses) using a hot plate system was assessed by infrared thermography and thermal conta…